Universität zu Köln

Skrobo, Benedikt and Deska, Jan ORCID: 0000-0003-4622-2365 (2013). Oxonium Ylide Rearrangement of Enzymatically Desymmetrized Glutarates. Org. Lett., 15 (23). S. 5998 - 6002. WASHINGTON: AMER CHEMICAL SOC. ISSN 1523-7052

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Abstract

The combination of an enzyme-mediated enantioselective desymmetrization of readily available 3-benzyloxyglutarates and subsequent rhodium-catalyzed oxonium ylide rearrangement of their corresponding in situ derived diazo ketones offers a very concise and highly stereoselective access to functionalized tetrahydrofuranone building blocks.

Item Type:	Journal Article
Creators:	Creators Email ORCID ORCID Put Code Skrobo, Benedikt UNSPECIFIED UNSPECIFIED UNSPECIFIED Deska, Jan UNSPECIFIED orcid.org/0000-0003-4622-2365 UNSPECIFIED
URN:	urn:nbn:de:hbz:38-470252
DOI:	10.1021/ol402887z
Journal or Publication Title:	Org. Lett.
Volume:	15
Number:	23
Page Range:	S. 5998 - 6002
Date:	2013
Publisher:	AMER CHEMICAL SOC
Place of Publication:	WASHINGTON
ISSN:	1523-7052
Language:	English
Faculty:	Unspecified
Divisions:	Unspecified
Subjects:	no entry
Uncontrolled Keywords:	Keywords Language MESO-ANHYDRIDES; ENANTIOSELECTIVE DESYMMETRIZATION; CATALYST; DIAZOMETHANE; ACIDS Multiple languages Chemistry, Organic Multiple languages
URI:	http://kups.ub.uni-koeln.de/id/eprint/47025