Universität zu Köln

Skrobo, Benedikt and Deska, Jan ORCID: 0000-0003-4622-2365 (2013). On the lipase-catalyzed resolution of functionalized biaryls. Tetrahedron-Asymmetry, 24 (17). S. 1052 - 1057. OXFORD: PERGAMON-ELSEVIER SCIENCE LTD. ISSN 0957-4166

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Abstract

The implementation of lipase catalysis as a tool for the preparation of optically active biaryls is discussed. While attempts toward dynamic kinetic resolution based on the catalytic ring opening of configurationally unstable biaryl lactones were fruitless, kinetic resolution via transesterification of hydroxymethyl-decorated substrates was successfully employed in the generation of optically enriched, axially chiral biaryls. (C) 2013 Elsevier Ltd. All rights reserved.

Item Type:	Journal Article
Creators:	Creators Email ORCID ORCID Put Code Skrobo, Benedikt UNSPECIFIED UNSPECIFIED UNSPECIFIED Deska, Jan UNSPECIFIED orcid.org/0000-0003-4622-2365 UNSPECIFIED
URN:	urn:nbn:de:hbz:38-475905
DOI:	10.1016/j.tetasy.2013.07.014
Journal or Publication Title:	Tetrahedron-Asymmetry
Volume:	24
Number:	17
Page Range:	S. 1052 - 1057
Date:	2013
Publisher:	PERGAMON-ELSEVIER SCIENCE LTD
Place of Publication:	OXFORD
ISSN:	0957-4166
Language:	English
Faculty:	Unspecified
Divisions:	Unspecified
Subjects:	no entry
Uncontrolled Keywords:	Keywords Language ATROPO-DIASTEREOSELECTIVE CLEAVAGE; CHIRAL NATURAL-PRODUCTS; FACILE SYNTHESIS; LACTONE CONCEPT; DESYMMETRIZATION; NUCLEOPHILES; PRECURSORS; REAGENTS Multiple languages Chemistry, Inorganic & Nuclear; Chemistry, Organic; Chemistry, Physical Multiple languages
URI:	http://kups.ub.uni-koeln.de/id/eprint/47590