Universität zu Köln

Romanski, Steffen, Neudoerfl, Joerg-M. and Schmalz, Hans-Guenther ORCID: 0000-0003-0489-1827 (2011). (RS)-Tricarbonyl(eta(4)-1,3-diacetoxy-5,5-dimethylcyclohexa-1,3-diene) iron(0). Acta Crystallogr. Sect. E.-Crystallogr. Commun., 67. S. M1530 - 11. CHESTER: INT UNION CRYSTALLOGRAPHY. ISSN 2056-9890

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Abstract

In the title compound, [Fe(C12H16O4)(CO)(3)], the diene moiety of the molecule is virtually planar, with a C-C-C-C torsion angle of -1.4 (2)degrees. The six-membered ring exhibits a boat conformation, with torsion angles of 46.2 (2) and 46.5 (3)degrees for a double-bond and the two attached Csp(3) atoms. The Fe atom is coordinated to all four of the diene C atoms, with bond lengths between 2.041 (2) and 2.117 (2) angstrom. The Fe(CO)(3) tripod adopts a conformation with one CO ligand eclipsing the Csp(3) - Csp(3) single bond.

Item Type:	Journal Article
Creators:	Creators Email ORCID ORCID Put Code Romanski, Steffen UNSPECIFIED UNSPECIFIED UNSPECIFIED Neudoerfl, Joerg-M. UNSPECIFIED UNSPECIFIED UNSPECIFIED Schmalz, Hans-Guenther UNSPECIFIED orcid.org/0000-0003-0489-1827 UNSPECIFIED
URN:	urn:nbn:de:hbz:38-486493
DOI:	10.1107/S1600536811041298
Journal or Publication Title:	Acta Crystallogr. Sect. E.-Crystallogr. Commun.
Volume:	67
Page Range:	S. M1530 - 11
Date:	2011
Publisher:	INT UNION CRYSTALLOGRAPHY
Place of Publication:	CHESTER
ISSN:	2056-9890
Language:	English
Faculty:	Unspecified
Divisions:	Unspecified
Subjects:	no entry
Uncontrolled Keywords:	Keywords Language CO Multiple languages Crystallography Multiple languages
URI:	http://kups.ub.uni-koeln.de/id/eprint/48649