Universität zu Köln

Beran, Martin and Meyer, Gerd (2011). Crystal Structure of Na3MoCl6. Crystals, 1 (3). S. 99 - 104. BASEL: MDPI. ISSN 2073-4352

Full text not available from this repository.

Abstract

The ternary chloride Na3MoCl6 is obtained as red crystals from a disproportionation reaction of molybdenum dichloride, {Mo-6} Cl-12, in an acidic NaCl/AlCl3 melt at 350 degrees C. The crystal structure (trigonal, P-31c, a = 687.1(1), c = 1225.3(2) pm, Z = 2, V = 501,0(1) 10(6) pm(3)) is that of Na3CrCl6: within a hexagonal closest-packing of chloride ions two thirds of the octahedral voids are filled between the AB double layers with Na+/ Mo3+, and between the BA layers with Na+.

Item Type:	Journal Article
Creators:	Creators Email ORCID ORCID Put Code Beran, Martin UNSPECIFIED UNSPECIFIED UNSPECIFIED Meyer, Gerd UNSPECIFIED UNSPECIFIED UNSPECIFIED
URN:	urn:nbn:de:hbz:38-490210
DOI:	10.3390/cryst1030099
Journal or Publication Title:	Crystals
Volume:	1
Number:	3
Page Range:	S. 99 - 104
Date:	2011
Publisher:	MDPI
Place of Publication:	BASEL
ISSN:	2073-4352
Language:	English
Faculty:	Unspecified
Divisions:	Unspecified
Subjects:	no entry
Uncontrolled Keywords:	Keywords Language TERNARY HALIDES Multiple languages Crystallography; Materials Science, Multidisciplinary Multiple languages
URI:	http://kups.ub.uni-koeln.de/id/eprint/49021