Universität zu Köln

Demir, Selvan ORCID: 0000-0001-7983-9850, Montalvo, Elizabeth, Ziller, Joseph W., Meyer, Gerd ORCID: 0000-0003-1000-9001 and Evans, William J. (2010). Facile Insertion of N2O into Metal-Carbon Bonds of Metallocene Allyl Complexes to Form (RN2O)(-) Ligands. Organometallics, 29 (23). S. 6608 - 6612. WASHINGTON: AMER CHEMICAL SOC. ISSN 1520-6041

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Abstract

Attempts to generate a scandium metallocene oxide using N2O have revealed that N2O undergoes facile insertion into metal carbon bonds of allyl meiallocene complexes to form (RN2O)(-) ligands where R = C3H5. This has been demonstrated in reactions with the tetramethylcyclopentadienyl allyl complexes (C5Me4H)(2)M(eta(3)-C3H5)(M = Sc, Y) and the pentamethylcyclopentadienyl allyl compounds (C5Me5)(2)M(eta(3)-C3H5) (M = Y, Sm, La), which generate the insertion products [(C5Me4H)(2)M(mu-eta(1):eta(2)-ON=NC3H5)](2) (M = Sc, 1; Y, 2) and [(C5Me5)(2)M(mu-eta(1):eta(2)-ON=NC3H5)](2)(M = Y, 3; Sm, 4; La, 5), respectively.

Item Type:	Journal Article
Creators:	Creators Email ORCID ORCID Put Code Demir, Selvan UNSPECIFIED orcid.org/0000-0001-7983-9850 UNSPECIFIED Montalvo, Elizabeth UNSPECIFIED UNSPECIFIED UNSPECIFIED Ziller, Joseph W. UNSPECIFIED UNSPECIFIED UNSPECIFIED Meyer, Gerd UNSPECIFIED orcid.org/0000-0003-1000-9001 UNSPECIFIED Evans, William J. UNSPECIFIED UNSPECIFIED UNSPECIFIED
URN:	urn:nbn:de:hbz:38-490681
DOI:	10.1021/om100917w
Journal or Publication Title:	Organometallics
Volume:	29
Number:	23
Page Range:	S. 6608 - 6612
Date:	2010
Publisher:	AMER CHEMICAL SOC
Place of Publication:	WASHINGTON
ISSN:	1520-6041
Language:	English
Faculty:	Unspecified
Divisions:	Unspecified
Subjects:	no entry
Uncontrolled Keywords:	Keywords Language X-RAY; STRUCTURAL-CHARACTERIZATION; OXYGEN-ATOM; LANTHANIDE; REACTIVITY; REDUCTION; YTTRIUM; SULFUR; OXIDE; OXO Multiple languages Chemistry, Inorganic & Nuclear; Chemistry, Organic Multiple languages
URI:	http://kups.ub.uni-koeln.de/id/eprint/49068