Demir, Selvan ORCID: 0000-0001-7983-9850, Montalvo, Elizabeth, Ziller, Joseph W., Meyer, Gerd ORCID: 0000-0003-1000-9001 and Evans, William J. (2010). Facile Insertion of N2O into Metal-Carbon Bonds of Metallocene Allyl Complexes to Form (RN2O)(-) Ligands. Organometallics, 29 (23). S. 6608 - 6612. WASHINGTON: AMER CHEMICAL SOC. ISSN 1520-6041

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Abstract

Attempts to generate a scandium metallocene oxide using N2O have revealed that N2O undergoes facile insertion into metal carbon bonds of allyl meiallocene complexes to form (RN2O)(-) ligands where R = C3H5. This has been demonstrated in reactions with the tetramethylcyclopentadienyl allyl complexes (C5Me4H)(2)M(eta(3)-C3H5)(M = Sc, Y) and the pentamethylcyclopentadienyl allyl compounds (C5Me5)(2)M(eta(3)-C3H5) (M = Y, Sm, La), which generate the insertion products [(C5Me4H)(2)M(mu-eta(1):eta(2)-ON=NC3H5)](2) (M = Sc, 1; Y, 2) and [(C5Me5)(2)M(mu-eta(1):eta(2)-ON=NC3H5)](2)(M = Y, 3; Sm, 4; La, 5), respectively.

Item Type: Journal Article
Creators:
CreatorsEmailORCIDORCID Put Code
Demir, SelvanUNSPECIFIEDorcid.org/0000-0001-7983-9850UNSPECIFIED
Montalvo, ElizabethUNSPECIFIEDUNSPECIFIEDUNSPECIFIED
Ziller, Joseph W.UNSPECIFIEDUNSPECIFIEDUNSPECIFIED
Meyer, GerdUNSPECIFIEDorcid.org/0000-0003-1000-9001UNSPECIFIED
Evans, William J.UNSPECIFIEDUNSPECIFIEDUNSPECIFIED
URN: urn:nbn:de:hbz:38-490681
DOI: 10.1021/om100917w
Journal or Publication Title: Organometallics
Volume: 29
Number: 23
Page Range: S. 6608 - 6612
Date: 2010
Publisher: AMER CHEMICAL SOC
Place of Publication: WASHINGTON
ISSN: 1520-6041
Language: English
Faculty: Unspecified
Divisions: Unspecified
Subjects: no entry
Uncontrolled Keywords:
KeywordsLanguage
X-RAY; STRUCTURAL-CHARACTERIZATION; OXYGEN-ATOM; LANTHANIDE; REACTIVITY; REDUCTION; YTTRIUM; SULFUR; OXIDE; OXOMultiple languages
Chemistry, Inorganic & Nuclear; Chemistry, OrganicMultiple languages
URI: http://kups.ub.uni-koeln.de/id/eprint/49068

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