Schurz, Christian M., Schleid, Thomas and Meyer, Gerd ORCID: 0000-0003-1000-9001 (2010). K2LaCl5. Acta Crystallogr. Sect. E.-Struct Rep. Online, 66. S. I78 - 10. MALDEN: WILEY-BLACKWELL. ISSN 1600-5368
Full text not available from this repository.Abstract
The ternary title compound, dipotassium lanthanum pentachloride, K2LaCl5, is isotypic with Y2HfS5 and various ternary rare-earth metal(III) halides with the general formula A(2)MX(5) (A = NH4, In-I, Na-Cs; M = La-Dy; X = Cl-I). The La3+ cations and three of the four symmetry-independent chloride anions are located on a crystallographic mirror plane. The La3+ cations are surrounded by seven chloride anions, each in the shape of a monocapped trigonal prism, whereas the coordination spheres of the K+ cations exhibit one more cap. Three of the four independent chloride anions reside in a fivefold cationic coordination, leading to distorted square pyramids. The fourth chloride anion has only four cationic neighbours, forming no specific polyhedron.
Item Type: | Journal Article | ||||||||||||||||
Creators: |
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URN: | urn:nbn:de:hbz:38-491020 | ||||||||||||||||
DOI: | 10.1107/S1600536810045198 | ||||||||||||||||
Journal or Publication Title: | Acta Crystallogr. Sect. E.-Struct Rep. Online | ||||||||||||||||
Volume: | 66 | ||||||||||||||||
Page Range: | S. I78 - 10 | ||||||||||||||||
Date: | 2010 | ||||||||||||||||
Publisher: | WILEY-BLACKWELL | ||||||||||||||||
Place of Publication: | MALDEN | ||||||||||||||||
ISSN: | 1600-5368 | ||||||||||||||||
Language: | English | ||||||||||||||||
Faculty: | Unspecified | ||||||||||||||||
Divisions: | Unspecified | ||||||||||||||||
Subjects: | no entry | ||||||||||||||||
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URI: | http://kups.ub.uni-koeln.de/id/eprint/49102 |
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