Universität zu Köln

Griesbeck, Axel G. and Bozkus, Seyma (2021). Spin Photochemistry: Electron Spin Multiplicity as a Tool for Reactivity and Selectivity Control. Chimia, 75 (10). S. 868 - 873. BERN: SWISS CHEMICAL SOC. ISSN 0009-4293

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Abstract

Spin chemistry involving small organic molecules without heavy atoms is highly sensitive to spin-orbit-coupling (SOC) modulating biradical conformation as well as hyperfine coupling (HFC) modulating magnetic isotope interactions. Several easily available reaction properties such as chemo-, regio-, and diastereoselectivity as well as quantum yields serve as analytical tools to follow intersystem crossing (ISC) dynamics and allow titrating spin selectivities.

Item Type:	Journal Article
Creators:	Creators Email ORCID ORCID Put Code Griesbeck, Axel G. UNSPECIFIED UNSPECIFIED UNSPECIFIED Bozkus, Seyma UNSPECIFIED UNSPECIFIED UNSPECIFIED
URN:	urn:nbn:de:hbz:38-562570
DOI:	10.2533/chimia.2021.868
Journal or Publication Title:	Chimia
Volume:	75
Number:	10
Page Range:	S. 868 - 873
Date:	2021
Publisher:	SWISS CHEMICAL SOC
Place of Publication:	BERN
ISSN:	0009-4293
Language:	English
Faculty:	Unspecified
Divisions:	Unspecified
Subjects:	no entry
Uncontrolled Keywords:	Keywords Language TRIPLET 1,4-BIRADICALS; CHEMISTRY; STEREOSELECTIVITY; STATE Multiple languages Chemistry, Multidisciplinary Multiple languages
URI:	http://kups.ub.uni-koeln.de/id/eprint/56257