Kaas, Marina, Werker, Melanie, Korber, Nikolaus and Ruschewitz, Uwe ORCID: 0000-0002-6511-6894 (2021). Reconfirmation of Solubility of C-2(2-) in Liquid Ammonia: Syntheses and Crystal Structures of the Tetrahedral Acetylide Ammoniates [Zn(C2H)(4)](2-), [Cd(C2H)(4)](2-) and [In(C6H5)(3)(C2H)] (-). Z. Anorg. Allg. Chem., 647 (22). S. 2001 - 2006. WEINHEIM: WILEY-V C H VERLAG GMBH. ISSN 1521-3749
Full text not available from this repository.Abstract
The new compounds with the sum formulae [Cs([18]crown-6)](2)[Zn(C2H)(4)] . 8NH(3), Rb-3[Rb([18]crown-6)(NH3)][Cd(C2H)(4)](2) . {[18]crown-6 . 2NH(3)} . NH3 and [Cs([2.2.2]crypt)][In(C6H5)(3)(C2H)] were synthesized in liquid ammonia. The anionic units show tetrahedrally coordinated central atoms with four hydrogenacetylide ligands or one C2H- and three C6H5- ligands. Solid state starting materials for these ligands were either AC(2)H (A=Rb, Cs) or Cs2C2. The fact that the indium compound contains a hydrogenacetylide ligand, which was formed from Cs2C2, confirms again the equilibrium of the species C2H2, C2H- and C-2(2-) in liquid ammonia and again proves that acetylides slowly dissolve in this medium.
Item Type: | Journal Article | ||||||||||||||||||||
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URN: | urn:nbn:de:hbz:38-570305 | ||||||||||||||||||||
DOI: | 10.1002/zaac.202100191 | ||||||||||||||||||||
Journal or Publication Title: | Z. Anorg. Allg. Chem. | ||||||||||||||||||||
Volume: | 647 | ||||||||||||||||||||
Number: | 22 | ||||||||||||||||||||
Page Range: | S. 2001 - 2006 | ||||||||||||||||||||
Date: | 2021 | ||||||||||||||||||||
Publisher: | WILEY-V C H VERLAG GMBH | ||||||||||||||||||||
Place of Publication: | WEINHEIM | ||||||||||||||||||||
ISSN: | 1521-3749 | ||||||||||||||||||||
Language: | English | ||||||||||||||||||||
Faculty: | Unspecified | ||||||||||||||||||||
Divisions: | Unspecified | ||||||||||||||||||||
Subjects: | no entry | ||||||||||||||||||||
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URI: | http://kups.ub.uni-koeln.de/id/eprint/57030 |
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