Brune, Veronika ORCID: 0000-0001-5909-621X, Raydan, Nidal, Sutorius, Anja, Hartl, Fabian, Purohit, Bhagyesh ORCID: 0000-0002-0247-0036, Gahlot, Sweta, Bargiela, Pascal, Burel, Laurence, Wilhelm, Michael ORCID: 0000-0002-4764-6955, Hegemann, Corinna, Atamturk, Ufuk, Mathur, Sanjay and Mishra, Shashank ORCID: 0000-0003-2846-4221 (2021). Single source precursor route to nanometric tin chalcogenides. Dalton Trans., 50 (46). S. 17346 - 17361. CAMBRIDGE: ROYAL SOC CHEMISTRY. ISSN 1477-9234

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Abstract

Low-temperature solution phase synthesis of nanomaterials using designed molecular precursors enjoys tremendous advantages over traditional high-temperature solid-state synthesis. These include atomic-level control over stoichiometry, homogeneous elemental dispersion and uniformly distributed nanoparticles. For exploiting these advantages, however, rationally designed molecular complexes having certain properties are usually required. We report here the synthesis and complete characterization of new molecular precursors containing direct Sn-E bonds (E = S or Se), which undergo facile decomposition under different conditions (solid/solution phase, thermal/microwave heating, single/mixed solvents, varying temperatures, etc.) to afford phase-pure or mixed-phase tin chalcogenide nanoflakes with defined ratios.

Item Type: Journal Article
Creators:
CreatorsEmailORCIDORCID Put Code
Brune, VeronikaUNSPECIFIEDorcid.org/0000-0001-5909-621XUNSPECIFIED
Raydan, NidalUNSPECIFIEDUNSPECIFIEDUNSPECIFIED
Sutorius, AnjaUNSPECIFIEDUNSPECIFIEDUNSPECIFIED
Hartl, FabianUNSPECIFIEDUNSPECIFIEDUNSPECIFIED
Purohit, BhagyeshUNSPECIFIEDorcid.org/0000-0002-0247-0036UNSPECIFIED
Gahlot, SwetaUNSPECIFIEDUNSPECIFIEDUNSPECIFIED
Bargiela, PascalUNSPECIFIEDUNSPECIFIEDUNSPECIFIED
Burel, LaurenceUNSPECIFIEDUNSPECIFIEDUNSPECIFIED
Wilhelm, MichaelUNSPECIFIEDorcid.org/0000-0002-4764-6955UNSPECIFIED
Hegemann, CorinnaUNSPECIFIEDUNSPECIFIEDUNSPECIFIED
Atamturk, UfukUNSPECIFIEDUNSPECIFIEDUNSPECIFIED
Mathur, SanjayUNSPECIFIEDUNSPECIFIEDUNSPECIFIED
Mishra, ShashankUNSPECIFIEDorcid.org/0000-0003-2846-4221UNSPECIFIED
URN: urn:nbn:de:hbz:38-578469
DOI: 10.1039/d1dt02964a
Journal or Publication Title: Dalton Trans.
Volume: 50
Number: 46
Page Range: S. 17346 - 17361
Date: 2021
Publisher: ROYAL SOC CHEMISTRY
Place of Publication: CAMBRIDGE
ISSN: 1477-9234
Language: English
Faculty: Unspecified
Divisions: Unspecified
Subjects: no entry
Uncontrolled Keywords:
KeywordsLanguage
STABILIZED TIN(II) COMPOUNDS; METAL OXIDATION-STATE; THIN-FILMS; ETHYLENE TRIMERIZATION; ELECTRICAL-PROPERTIES; MAIN-GROUP; SNSE; REACTIVITY; COMPLEXES; NANOPARTICLESMultiple languages
Chemistry, Inorganic & NuclearMultiple languages
URI: http://kups.ub.uni-koeln.de/id/eprint/57846

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