Universität zu Köln

Werner, Daniel, Badea, Desiree ORCID: 0000-0002-8837-9988, Schoenzart, Jasmin, Eimermacher, Sophia ORCID: 0000-0002-2311-3644, Baetz, Philipp, Wickleder, Mathias S. and Zegke, Markus (2022). Facile Solvent-Free Mechanochemical Synthesis of UI3 and Lanthanoid Iodides. Chemistry-Switz., 4 (4). S. 1672 - 1679. BASEL: MDPI. ISSN 2624-8549

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Abstract

Lewis base-free lanthanoid (Ln) and actinoid (An) iodides are difficult to obtain, as standard protocols describe syntheses in solutions of donor solvents which are ultimately hard to remove. We have now established a mechanochemical approach towards the synthesis of Lewis base-free f-block metal iodides with excellent yields. In particular, we describe herein the synthesis of EuI2 as an example of a divalent lanthanoid iodide, of CeI3 as an example of a trivalent lanthanoid iodide, and of UI3 as the most important actinoid iodide. Each can be obtained in high yield with minimal work-up, presenting the most efficient and simple synthetic route to access these materials to date.

Item Type:	Journal Article
Creators:	Creators Email ORCID ORCID Put Code Werner, Daniel UNSPECIFIED UNSPECIFIED UNSPECIFIED Badea, Desiree UNSPECIFIED orcid.org/0000-0002-8837-9988 UNSPECIFIED Schoenzart, Jasmin UNSPECIFIED UNSPECIFIED UNSPECIFIED Eimermacher, Sophia UNSPECIFIED orcid.org/0000-0002-2311-3644 UNSPECIFIED Baetz, Philipp UNSPECIFIED UNSPECIFIED UNSPECIFIED Wickleder, Mathias S. UNSPECIFIED UNSPECIFIED UNSPECIFIED Zegke, Markus UNSPECIFIED UNSPECIFIED UNSPECIFIED
URN:	urn:nbn:de:hbz:38-660258
DOI:	10.3390/chemistry4040108
Journal or Publication Title:	Chemistry-Switz.
Volume:	4
Number:	4
Page Range:	S. 1672 - 1679
Date:	2022
Publisher:	MDPI
Place of Publication:	BASEL
ISSN:	2624-8549
Language:	English
Faculty:	Unspecified
Divisions:	Unspecified
Subjects:	no entry
Uncontrolled Keywords:	Keywords Language SINGLE-MOLECULE MAGNET; COMPLEXES; URANIUM; REDUCTION; CHEMISTRY; ACTIVATION; TRIIODIDE; DIIODIDES; SERIES; UL(3) Multiple languages Chemistry, Multidisciplinary Multiple languages
URI:	http://kups.ub.uni-koeln.de/id/eprint/66025