Universität zu Köln

Rennebaum, Tobias ORCID: 0000-0003-0241-4680, van Gerven, David ORCID: 0000-0001-9712-551X and Wickleder, Mathias S. (2022). The Unprecedented [S4N2O10](2-) Anion in the Molecular Gold Complexes [Au2Br2(S4N2O10)(2)] and [Au2Cl2(S4N2O10)(2)](S2O5Cl2). Chem.-Eur. J., 28 (65). WEINHEIM: WILEY-V C H VERLAG GMBH. ISSN 1521-3765

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Abstract

The reaction of hexachlorophosphazene, P3N3Cl6, with SO3 and the gold halides AuCl3 and AuBr3, respectively, leads to the new cyclic anionic tetramer, [S4N2O10](2-), which is coordinated to Au3+ in the dimeric complexes [Au2X2(S4N2O10)(2)] (X=Cl, Br). The [S4N2O10](2-) anion can be seen as the condensation product of two sulfate anions, [SO4](2-)(,) and two amidosulfate anions, [NH2SO3](-).

Item Type:	Journal Article
Creators:	Creators Email ORCID ORCID Put Code Rennebaum, Tobias UNSPECIFIED orcid.org/0000-0003-0241-4680 UNSPECIFIED van Gerven, David UNSPECIFIED orcid.org/0000-0001-9712-551X UNSPECIFIED Wickleder, Mathias S. UNSPECIFIED UNSPECIFIED UNSPECIFIED
URN:	urn:nbn:de:hbz:38-660293
DOI:	10.1002/chem.202202171
Journal or Publication Title:	Chem.-Eur. J.
Volume:	28
Number:	65
Date:	2022
Publisher:	WILEY-V C H VERLAG GMBH
Place of Publication:	WEINHEIM
ISSN:	1521-3765
Language:	English
Faculty:	Unspecified
Divisions:	Unspecified
Subjects:	no entry
Uncontrolled Keywords:	Keywords Language CRYSTAL-STRUCTURE; REFINEMENT; GOLD(III); CHEMISTRY Multiple languages Chemistry, Multidisciplinary Multiple languages
URI:	http://kups.ub.uni-koeln.de/id/eprint/66029