Universität zu Köln

Zimmermann, Vanessa, Schindler, Lisa, V, van Gerven, David and Wickleder, Mathias S. (2022). The reaction of NH4Cl with SO3: Two modifications of (NH4)[SO3Cl]. Z. Anorg. Allg. Chem., 648 (24). WEINHEIM: WILEY-V C H VERLAG GMBH. ISSN 1521-3749

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Abstract

The reaction of NH4Cl with SO3 leads to the chlorosulfate (NH4)[SO3Cl]. Depending on the reaction temperature two different modifications are obtained. At 80 degrees C the orthorhombic modification (NH4)[SO3Cl]-I is obtained (Pbca, Z=16, a=1078.03(4), b=911.55(3), c=1915.32(6), V-m=70.85 cm(3)/mol), at 120 degrees C monoclinic (NH4)[SO3Cl]-II forms (P2(1)/c, Z=8, a=846.19(3), b=590.30(2), c=852.29(7) pm, beta=100.516(10)degrees, V-m=68.48 cm(3)/mol). The observed bonds in the chlorosulfate anion are compared to the few know compounds of this type and to theoretical values based on DFT calculations.

Item Type:	Journal Article
Creators:	Creators Email ORCID ORCID Put Code Zimmermann, Vanessa UNSPECIFIED UNSPECIFIED UNSPECIFIED Schindler, Lisa, V UNSPECIFIED UNSPECIFIED UNSPECIFIED van Gerven, David UNSPECIFIED UNSPECIFIED UNSPECIFIED Wickleder, Mathias S. UNSPECIFIED UNSPECIFIED UNSPECIFIED
URN:	urn:nbn:de:hbz:38-661513
DOI:	10.1002/zaac.202200238
Journal or Publication Title:	Z. Anorg. Allg. Chem.
Volume:	648
Number:	24
Date:	2022
Publisher:	WILEY-V C H VERLAG GMBH
Place of Publication:	WEINHEIM
ISSN:	1521-3749
Language:	English
Faculty:	Unspecified
Divisions:	Unspecified
Subjects:	no entry
Uncontrolled Keywords:	Keywords Language CORRELATED MOLECULAR CALCULATIONS; GAUSSIAN-BASIS SETS; CRYSTAL-STRUCTURE; INFRARED-SPECTRA; LITHIUM; RAMAN Multiple languages Chemistry, Inorganic & Nuclear Multiple languages
URI:	http://kups.ub.uni-koeln.de/id/eprint/66151