Nickelsen, Jasper ORCID: 0000-0001-6356-5277, van Gerven, David ORCID: 0000-0001-9712-551X and Wickleder, Mathias S. (2022). In situ single crystal growth of tris(trimethylsilyl)phosphate, (Me3SiO)(3)PO. Z. Anorg. Allg. Chem., 648 (18). WEINHEIM: WILEY-V C H VERLAG GMBH. ISSN 1521-3749
Full text not available from this repository.Abstract
(Me3SiO)(3)PO has been prepared by the reaction of Na[H2PO4] and (Me3Si)Cl. Crystallization of the liquid was successful using an Optical Heating and Crystallization Device (OHCD) and allow the determination of the crystal structure of the compound (monoclinic, P2(1), Z=4), a=1016.67(6) pm, b=1053.70(6) pm, c=1759.2(1) pm, beta=91.916(2)degrees, wR(2)=0.0979). The molecular structure shows the phosphorous atom tetrahedrally coordinated by three (Me3SiO) groups and one oxygen atom. The compound can be seen as a missing link between the related cation and anion [(Me3SiO)(4)P](+) and [(Me3SiO)(2)PO2](-), respectively.
Item Type: | Journal Article | ||||||||||||||||
Creators: |
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URN: | urn:nbn:de:hbz:38-661839 | ||||||||||||||||
DOI: | 10.1002/zaac.202200184 | ||||||||||||||||
Journal or Publication Title: | Z. Anorg. Allg. Chem. | ||||||||||||||||
Volume: | 648 | ||||||||||||||||
Number: | 18 | ||||||||||||||||
Date: | 2022 | ||||||||||||||||
Publisher: | WILEY-V C H VERLAG GMBH | ||||||||||||||||
Place of Publication: | WEINHEIM | ||||||||||||||||
ISSN: | 1521-3749 | ||||||||||||||||
Language: | English | ||||||||||||||||
Faculty: | Unspecified | ||||||||||||||||
Divisions: | Unspecified | ||||||||||||||||
Subjects: | no entry | ||||||||||||||||
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URI: | http://kups.ub.uni-koeln.de/id/eprint/66183 |
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