Universität zu Köln

Nickelsen, Jasper ORCID: 0000-0001-6356-5277, van Gerven, David ORCID: 0000-0001-9712-551X and Wickleder, Mathias S. (2022). In situ single crystal growth of tris(trimethylsilyl)phosphate, (Me3SiO)(3)PO. Z. Anorg. Allg. Chem., 648 (18). WEINHEIM: WILEY-V C H VERLAG GMBH. ISSN 1521-3749

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Abstract

(Me3SiO)(3)PO has been prepared by the reaction of Na[H2PO4] and (Me3Si)Cl. Crystallization of the liquid was successful using an Optical Heating and Crystallization Device (OHCD) and allow the determination of the crystal structure of the compound (monoclinic, P2(1), Z=4), a=1016.67(6) pm, b=1053.70(6) pm, c=1759.2(1) pm, beta=91.916(2)degrees, wR(2)=0.0979). The molecular structure shows the phosphorous atom tetrahedrally coordinated by three (Me3SiO) groups and one oxygen atom. The compound can be seen as a missing link between the related cation and anion [(Me3SiO)(4)P](+) and [(Me3SiO)(2)PO2](-), respectively.

Item Type:	Journal Article
Creators:	Creators Email ORCID ORCID Put Code Nickelsen, Jasper UNSPECIFIED orcid.org/0000-0001-6356-5277 UNSPECIFIED van Gerven, David UNSPECIFIED orcid.org/0000-0001-9712-551X UNSPECIFIED Wickleder, Mathias S. UNSPECIFIED UNSPECIFIED UNSPECIFIED
URN:	urn:nbn:de:hbz:38-661839
DOI:	10.1002/zaac.202200184
Journal or Publication Title:	Z. Anorg. Allg. Chem.
Volume:	648
Number:	18
Date:	2022
Publisher:	WILEY-V C H VERLAG GMBH
Place of Publication:	WEINHEIM
ISSN:	1521-3749
Language:	English
Faculty:	Unspecified
Divisions:	Unspecified
Subjects:	no entry
Uncontrolled Keywords:	Keywords Language Chemistry, Inorganic & Nuclear Multiple languages
URI:	http://kups.ub.uni-koeln.de/id/eprint/66183