Universität zu Köln

Li, Man-Rong ORCID: 0000-0001-8424-9134, Croft, Mark, Stephens, Peter W., Ye, Meng ORCID: 0000-0003-2814-6071, Vanderbilt, David ORCID: 0000-0002-2465-9091, Retuerto, Maria ORCID: 0000-0001-7564-3500, Deng, Zheng, Grams, Christoph P., Hemberger, Joachim, Hadermann, Joke ORCID: 0000-0002-1756-2566, Li, Wen-Min, Jin, Chang-Qing, Saouma, Felix O. ORCID: 0000-0002-9413-1866, Jang, Joon I., Akamatsu, Hirofumi ORCID: 0000-0003-2867-2127, Gopalan, Venkatraman, Walker, David and Greenblatt, Martha (2015). Mn2FeWO6: A New Ni3TeO6-Type Polar and Magnetic Oxide. Adv. Mater., 27 (13). S. 2177 - 2183. WEINHEIM: WILEY-V C H VERLAG GMBH. ISSN 1521-4095

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Abstract

Mn22+Fe2+W6+O6, a new polar magnetic phase, adopts the corundum-derived Ni3TeO6-type structure with large spontaneous polarization (P-S) of 67.8 mu C cm-2, complex antiferromagnetic order below approximate to 75 K, and field-induced first-order transition to a ferrimagnetic phase below approximate to 30 K. First-principles calculations predict a ferrimagnetic (udu) ground state, optimal switching path along the c-axis, and transition to a lower energy udu-udd magnetic double cell.

Item Type:	Journal Article
Creators:	Creators Email ORCID ORCID Put Code Li, Man-Rong UNSPECIFIED orcid.org/0000-0001-8424-9134 UNSPECIFIED Croft, Mark UNSPECIFIED UNSPECIFIED UNSPECIFIED Stephens, Peter W. UNSPECIFIED UNSPECIFIED UNSPECIFIED Ye, Meng UNSPECIFIED orcid.org/0000-0003-2814-6071 UNSPECIFIED Vanderbilt, David UNSPECIFIED orcid.org/0000-0002-2465-9091 UNSPECIFIED Retuerto, Maria UNSPECIFIED orcid.org/0000-0001-7564-3500 UNSPECIFIED Deng, Zheng UNSPECIFIED UNSPECIFIED UNSPECIFIED Grams, Christoph P. UNSPECIFIED UNSPECIFIED UNSPECIFIED Hemberger, Joachim UNSPECIFIED UNSPECIFIED UNSPECIFIED Hadermann, Joke UNSPECIFIED orcid.org/0000-0002-1756-2566 UNSPECIFIED Li, Wen-Min UNSPECIFIED UNSPECIFIED UNSPECIFIED Jin, Chang-Qing UNSPECIFIED UNSPECIFIED UNSPECIFIED Saouma, Felix O. UNSPECIFIED orcid.org/0000-0002-9413-1866 UNSPECIFIED Jang, Joon I. UNSPECIFIED UNSPECIFIED UNSPECIFIED Akamatsu, Hirofumi UNSPECIFIED orcid.org/0000-0003-2867-2127 UNSPECIFIED Gopalan, Venkatraman UNSPECIFIED UNSPECIFIED UNSPECIFIED Walker, David UNSPECIFIED UNSPECIFIED UNSPECIFIED Greenblatt, Martha UNSPECIFIED UNSPECIFIED UNSPECIFIED
URN:	urn:nbn:de:hbz:38-408804
DOI:	10.1002/adma.201405244
Journal or Publication Title:	Adv. Mater.
Volume:	27
Number:	13
Page Range:	S. 2177 - 2183
Date:	2015
Publisher:	WILEY-V C H VERLAG GMBH
Place of Publication:	WEINHEIM
ISSN:	1521-4095
Language:	English
Faculty:	Faculty of Mathematics and Natural Sciences
Divisions:	Faculty of Mathematics and Natural Sciences > Department of Physics > Institute of Physics II
Subjects:	no entry
Uncontrolled Keywords:	Keywords Language CORUNDUM; TELLURATES; LINBO3; ZNSNO3 Multiple languages Chemistry, Multidisciplinary; Chemistry, Physical; Nanoscience & Nanotechnology; Materials Science, Multidisciplinary; Physics, Applied; Physics, Condensed Matter Multiple languages
Refereed:	Yes
URI:	http://kups.ub.uni-koeln.de/id/eprint/40880